Hi Toocrazy_allday
the throttle has no interaction with the controller, so whatever you set is in no relation to the LEDs there. What the throttle shows you are the voltage levels (a so called window) Wuxing or anyone defined as "safe" unaware of the voltage level you are using (so there are three different throttles available 24/36/48). If you change the battery (24 vs 48V) the throttle does not know.
As example: A LFP (LiFePO4) with 12S is 95% fully charged with 12*3,3V=>39,6V and 100% (overcharged already) with 12*3,6V=>43,2V, deepcharged with 2,8V*12=>33,6V and discharged with 5-10% remaining at 3,2V=>38,4V. So the right windows to show would be 38,4V - 39,6V as everything happy. LTO+LFP chemistry has the smallest window (about 100mV per Cell) of all Lithium based batteries. While LiPO differ 1V from charged/Discharged, LiIon allow 2,5-4.2V per Cell.
What you have on your throttle is a "nice" disco for old people to stop damaging whatever battery. It's not a real gauge. Depending on the current, the lifecycle of your battery and the temperature the battery level changes quite a lot (LFP und LTO again no more than 1V for a 12S pack, while LiIon can drop up to 4V under the same load). There are really good small Cell-Loger available (cellLog e.g.) who do a very good job and allows even to diagnose it on PC how good your pack still is), which signal when any cell is below or above (LiPo+LiIon can burn when overcharged) their defined parameters.
To get more power out of the MP(x) simply upgrade the voltage, as the RPM is done via the voltage, not the currentflow. The current just do the power to be at a certain RPM in a certain time (or how big the incline could be).
Cheers
Sam