Hi Kim,
I think you are worrying unnecessarily, because I definitely don't see those results as "bad news".
If you ignore the values obtained while manually balancing the pack, compared to your original results
(Pre manual balancing) the pack has definitely improved significantly:
The difference between the highest and lowest cell
(was 280mV but now 210mV) has actually been reduced by 70mV, which is an overall improvement of 25%.
I suspect that another night on the charger
(without manual balancing) will improve them even more
(although it might only improve by a small amount) but I'm hopeful that the balance of the cells will continue to improve with regular charging.
The biggest problem with the manual balancing is the time it takes for each cell voltage to completely stabilise after you have manually topped it up, and the lower cells that have been topped up more, will typically drop more than the higher cells, even though you may have topped them all up to the exact same ~3.65V.
Even though the cell voltages will have dropped after they have fully stabilised, the resting cell voltages should still be nearer to the ~3.65V than they were before they were topped up.
Fortunately, the
BMS is able to add capacity
(using the same amount of current) to all of the low cells
simultaneously at the end of the charge
(but only when the charger cuts in again) therefore it
should gradually increase the voltage of
all the lower voltage cells if the battery is left charging for a long enough period of time.
The
BMS does not have to "chase rabbits" one at a time, it simply slows all the fast rabbits down, which allows the slower ones to gradually catch up.
Is the charger itself throwing the pack out of balance ?
It is definitely not the charger, as there is no way the charger could reduce the voltage of individual cells, only the
BMS has the ability to do that.
As previously stated, the
"post manual balancing" figures have definitely improved over the
"pre manual balancing" figures, which is a positive and reassuring result.
Alan