Putting a 24 and 36V battery in series would be too much voltage for the Pie's controller
(and the MPIII) because it would be over 70V (42V +29.4V) fully charged, but two identical 24V packs should be fine.
Basically, the capacitors in the controller are only rated for maximum safe voltage of 63V and any more than 63V would eventually result in their failure.
I carried out some basic tests on my original Magic Pie when I first had it to compare the maximum power from
14Ah SLA batteries and
Turnigy 5Ah 20C LiPo packs and I discovered then that the MKI Pie's controller would not even work at only 61.63Volts.
The tests were done by raising the wheel off the ground and then holding the throttle fully open and gradually applying the brake until the wheel was almost completely stopped.
These are the readings from my watt meter:
Battery No load voltage Max Amps Min Volts Max Wattage 24V SLA 25.76 20.14 23.09 465
25.9V LiPo 27.30 20.29 25.80 525
36V SLA 38.70 20.21 34.79 703
48V SLA 51.50 20.33 44.99 915
48.1V LiPo 50.30 19.85 47.75 949
55.5V LiPo 58.70 20.08 55.51 1115
59.2V LiPo 61.63 voltage was too high to test (the Pie refused to work!)If you have two or more batteries of identical voltage
(and type) you can either connect them in parallel, or simply plug each one in separately when required.
If you had a 48V and 36V pack, you could only use them one at a time by simply swapping the battery lead from one to the other.
Then you could use the 48V pack to get to work quickly, and then return home at a more leisurely pace using the 36V pack.
The current MPIII controller also uses 63V capacitors, so the MPIII is unlikely to support the higher voltages that it was originally expected to use.
Don't forget that when you use a higher voltage pack, you will use up more of your battery's energy fighting against the increased wind resistance at the higher speeds, so a pair of 24V batteries would probably take you much further in parallel than if they were wired in series.
Alan