Alan is right!
Unless you are want to do some very unusual stuff, it's just best to leave the build side alone & connect in parallel through the wire harness! Plus, you can pick & choose to take both or 1 or the other with you depending on the range needed for that trip! You can also connect on series later on if you get a controller that can handle it (96v) this way...
Really the only advantage is if you want to divide them up into small voltage packs that can be combined as above while also used in lower voltage packs like I want! Otherwise it's not really worth it...
Just be certain to ONLY use in combination if all packs are the same voltage (I prefer within 0.1-0.2v max difference & typically insist on identical voltages)! I have to disagree with allowing up to a full volt difference between packs, especially on life batteries... That's a recipe to destroy the batteries!
It's possible that by the time the higher voltage packs get to their low voltage cutoff, that the lower voltage pack can be discharged to unsafe levels! Or worse, that they are overcharged... In my opinion
BMSs & Smart chargers can't be entirely relied on to protect out of balance batteries/cells! I've seen plenty of times that they failed! That's why I prefer to measure things myself & monitor all directly!
Adam