"at 48V it will draw 25A, and 50A at 24V" - as for Amps, it's programmable in Controller... I meant that both of the systems may provide the same power to the bicycle (in ideal).
"includes wires and connectors" - I'm using 75A Anderson connectors and 10AWG wires ...
You don't say whether this is a hub motor or a mid-drive" - mid-drive motor
going to be a big difference in speed" - twice: for 48V is 500RPM, for 24V is 250RPM, but the final RPM might be compensated/adjusted by chain-wheel.
As for the 24"-wheel bicycle with gearing ration of 1.6, in ideal the max speed for 24V system (250RPM) would be nearly 45km/h:
(250*60)*(3.14*(24*2.54/100)/1000)*1.6=~45(km/h)
Your controller has to be capable of handling the higher currents as well" - it has, I'm going to purchase Kelly's Controller, which support up to 50A of continuous current and up to 120A in peeks.
Hmm... What's value of DC current starts to be dangerous?
A 24V 10AH battery is likely to give about the same range as a 48V 5AH and weigh something similar" - I'm not so sure... Will 24V 10Ah battery provide the same range as 96V 2.5Ah?
Since the Controller is programmable, it's always possible to play with a maximum allowed current... I think it's comparable with a driving style on the car - driving without kick-downs should save a lot of gas!
Please correct me if I'm wrong